INVESTIGATION OF THE LOWEST TRIPLET STATE OF THE PYROCHLOROPHYLLIDE a-APOMYOGLOBIN COMPLEX BY ZERO-FIELD OPTICALLY DETECTED MAGNETIC RESONANCE SPECTROSCOPY
نویسندگان
چکیده
The zero-lizld lluoresccnccdckctcd triplet state mpetlc reson3ncc spcctn hwc been obmincd for the pymchlorophyllidc a-apomyoglobm compln at 1 K The rnplct SICIIC zero-field sphltmgs Jnd spm sublevel dyn.mucs wcrc detcclcd on the rcsolwd features of the slrucrurcd lowtempcrzxture Iluoresccncc. Struclurrd ~luorcsccncc LS nol obscrvcd ior pyiuchlorophyhde a m XI atgzruc m3trLx under Idenricsl candlrions. Thrsc dara xc lnhxprcWd III wrms of Ihe loc.d bInding XI= of the pyrochlorophylhdc a chmmophorc ~II the pd& md the low-lcmper3lur2 conrornMon oi the protein lll3111\
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